Kalibrasi dan Validasi Model Spektrum Inframerah Biji Kopi untuk Pengujian Kadar Air (Moisture Content) dan Asam Klorogenat (Cholorogenic Acid) Biji Kopi Secara Non- Destruktif
DOI : DOI: 10.17969/jimfp.v7i4.22229
Date : 12 November 2022
Abstrak.ÃÂ KualitasÃÂ bijiÃÂ kopiÃÂ harusÃÂ memenuhiÃÂ standarisasiÃÂ mutusehinggaÃÂ dapatÃÂ diterimaÃÂ secaraÃÂ luasÃÂ olehÃÂ konsumen.ÃÂ KandungankimiaÃÂ danÃÂ mutuÃÂ bijiÃÂ kopiÃÂ berbeda-beda,ÃÂ tergantungÃÂ padaÃÂ jeniskopi,ÃÂ kondisiÃÂ tanahÃÂ tempatÃÂ tumbuh, prosesÃÂ pascapanen,ÃÂ pengolahanÃÂ kopi yangÃÂ tepatÃÂ danÃÂ suhuÃÂ lingkunganÃÂ tempatÃÂ kopiÃÂ tumbuh.ÃÂ TujuanÃÂ penelitianÃÂ iniÃÂ untukÃÂ membandingkanÃÂ nilaiprediksiÃÂ yangÃÂ didapatÃÂ dariÃÂ penggunaanÃÂ metodeÃÂ Partial Least SquareÃÂ (PLS)ÃÂ denganÃÂ metodeÃÂ Principal Component RegressionÃÂ (PCR)ÃÂ denganÃÂ Near Infrared Reflectance SpectroscopyÃÂ (NIRS)ÃÂ sertaÃÂ melakukanÃÂ kalibrasiÃÂ danÃÂ validasiÃÂ denganÃÂ modelÃÂ terdahulu.HasilÃÂ penelitianÃÂ iniÃÂ menunjukkanÃÂ bahwaÃÂ kalibrasiÃÂ menggunakanmetodeÃÂ PLSÃÂ padaÃÂ kandunganÃÂ kadarÃÂ airÃÂ mendapatÃÂ nilaiÃÂ koefisionkorelasiÃÂ (r)ÃÂ sebesarÃÂ 0,65ÃÂ danÃÂ RPDÃÂ sebesarÃÂ 1,37ÃÂ sedangkanÃÂ padakandunganÃÂ asamÃÂ klorogenatÃÂ mendapatÃÂ nilaiÃÂ koefisionÃÂ korelasi(r)ÃÂ sebesarÃÂ 0,95ÃÂ danÃÂ RPDÃÂ sebesarÃÂ 3,32.ÃÂ PadaÃÂ metodeÃÂ PCR, ÃÂ kandunganÃÂ kadarÃÂ airÃÂ mendapatÃÂ nilaiÃÂ koefisionÃÂ korelasiÃÂ (r)ÃÂ sebesarÃÂ 0,66ÃÂ danÃÂ RPDÃÂ sebesarÃÂ 1,42ÃÂ sedangkanÃÂ padaÃÂ kandunganasamÃÂ klorogenatÃÂ mendapatÃÂ nilaiÃÂ koefisionÃÂ korelasiÃÂ (r)ÃÂ sebesar0,93ÃÂ danÃÂ RPDÃÂ sebesarÃÂ 2,82.ÃÂ DariÃÂ hasilÃÂ pengujianÃÂ terhadapmodel,ÃÂ penggunaanÃÂ model PLSÃÂ lebihÃÂ unggulÃÂ dalamÃÂ memprediksikadarÃÂ airÃÂ danÃÂ asamÃÂ klorogenatÃÂ secaraÃÂ nonÃÂ destruktifÃÂ denganÃÂ nilaiprediksiÃÂ ÃÂ yangÃÂ masihÃÂ sesuaiÃÂ atauÃÂ masihÃÂ dalamÃÂ rangeÃÂ denganhasilÃÂ laboratoriumÃÂ yangÃÂ diperoleh.Calibration and Validation of Infrared Spectrum ModelÃÂ for Non-DestructiveÃÂ AnalysisÃÂ of Moisture Content andÃÂ ChlorogenicAcidÃÂ CoffeÃÂ BeansAbstract.ÃÂ The quality of coffee beans must meet quality standards so that they can be widely accepted by consumers. The chemical content and quality of coffee beans has different, depending on the type of coffee, the soil conditions in which it is grown, the post-harvest process, the proper processing of coffee and the temperature of the environment where the coffee is grown. The purpose of this study was to compare the predicted values obtained from the use of the Partial Least Square (PLS) method with the Principal Component Regression (PCR) method with Near Infrared Reflectance Spectroscopy (NIRS) as well as to calibrate and validate with the previous model. The results of this study indicate that the calibration using the PLS method on the water content gets a correlation coefficient (r) of 0.65 and an RPD of 1.37 while theÃÂ chlorogenicÃÂ acid content gets a correlation coefficient (r) of 0.95 and an RPD of 3 ,32. In the PCR method, the water content has a correlation coefficient (r) of 0.66 and an RPD of 1.42, while theÃÂ chlorogenicÃÂ acid content has a correlation coefficient (r) of 0.93 and an RPD of 2.82. From the results of testing the model, the use of the PLS model is superior in non-destructively predicting water andÃÂ chlorogenicacid content with predictive values that are still in line with or within the range of the obtained laboratory results.