Synthesis and Characterization New Polyurethane Membrane From Hydroxylated Rubber Seed Oil

Publication Name : ORIENTAL JOURNAL OF CHEMISTRY

DOI : 10.13005/ojc/330122

Date : FEB 2017


New polyurethane membrane from hydroxylated rubber seed oil has been prepared in this study. Hydroxylated process of rubber seed oil improved 135.30% of hydroxyl number and decreased 73.91% of iodine number of rubber seed oil. Optimum polyurethane membrane was obtained at the composition of hydroxylated rubber seed oil: hexamethylene-1,6-diisocyanate was 5: 7 v/w. The membrane was homogeneous, dry, smooth, slightly stiff and brownish yellow. The clean water flux and rejection factor of the membrane were 0,544L /m(2). h. bar and 98.86%, respectively. FTIR spectra indicated the formation of urethane bond (N-H at 3308 cm(-1)). Thermal analysis showed two stages of decomposition at 223 degrees C and 386 degrees C. The membrane exhibited a strong and elastic properties with a tensile strength of 1.13 kgf/mm(2) and elongation 215.36%.

Type
Journal
ISSN
0970-020X
EISSN
2231-5039
Page
199 - 206